1 edition of Solid Base Catalysis found in the catalog.
|Statement||by Yoshio Ono, Hideshi Hattori|
|Series||Springer Series in Chemical Physics -- 101|
|Contributions||Hattori, Hideshi, SpringerLink (Online service)|
|The Physical Object|
|Format||[electronic resource] /|
Potassium triphosphate is a surprisingly active catalyst for the catalytic transfer hydrogenation of carbonyl compounds. A pretreatment at °C is critical to obtain the active material. Temperature programmed desorption of CO2 indicates that sites of lower basicity were created after heat treatment for 5 h as compared to 1 h. With 2-propanol as hydride source, aromatic aldehydes were. In acid catalysis and base catalysis, a chemical reaction is catalyzed by an acid or a Brønsted–Lowry acid–base theory, the acid is the proton (hydrogen ion, H +) donor and the base is the proton l reactions catalyzed by proton transfer are esterfications and aldol these reactions, the conjugate acid of the carbonyl group is a better electrophile than.
Solid-base catalysis is covered by A. Corma and S. Iborra (Chapter 7). Reactions include Aldol and Knoevenagel condensations over hydrotalcites, alkaline earth oxides and base-modified silicas. Chapter 8, by S. Bailey and F. King, is extensive, covering hydrogenation and dehydrogenation, and is probably of most relevance to platinum group. 1-butene Acid amount mmol/g acid and base acid sites Acid strength H0 acid-base bifunctional acidic properties adsorbed adsorption alumina alumina catalysts aluminium amine titration method ammonia Amount and strength amount of acid amount of base anion atoms basic properties basic sites basic strength benzene Br0nsted acid bromothymol blue.
Description. The first book to focus on catalytic processes from the viewpoint of green chemistry presents all the important aspects. Written by Roger A. Sheldon and his co-workers, the result is an indispensable source for scientists looking to improve catalysis in both college and industry. Heterogeneous Catalysis I Introduction Catalysis is a term coined by Baron J. J. Berzelius in to describe the property ofsubstances that facilitate chemical reactions without being consumed in them. A broad definition of catalysis also allows for materials that slow the rate of a reac tion.
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The book is focused on the solid base. Because of the advantages over liquid bases, the use of solid base catalysts in organic synthesis is expanding. Solid bases are easier to dispose than liquid bases, separation and recovery of products, catalysts and solvents are less difficult, and they are by: 3.
The book is focused on the solid base. Because of the advantages over liquid bases, the use of solid base catalysts in organic synthesis is expanding.
Solid bases are easier to dispose than liquid bases, separation and recovery of products, catalysts and solvents are Solid Base Catalysis book difficult, and they are non-corrosive.
An excellent book describing acidity function, the main acid-type solid catalysts, their characterization, many details on reaction mechanisms, and their applications, it is very well documented and written homogenously, with an up-to-date analysis of the field.
The book is highly recommended for both young and established by: This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect: Numerous catalytic reductions and oxidations methods Solid-acid and solid-base catalysis.
Purchase Acid-Base Catalysis II, Volume 90 - 1st Edition. Print Book & E-Book. ISBNBook Edition: 1. In the field of solid base catalysts, the basic ch aracteristics, which include the number, location, and strength of basic sites on solid catalysts, are not easily determined.
Thus, the basic. His special field of interest is solid acid and base catalysis. catalyzed reactions, on the contrary, reactants act as acids toward catalysts which act as bases.
In homogeneous systems, a huge number of acid- Heterogeneous Basic Catalysis Chemical Reviews,Vol. 95, No. 3 I T-'. erogeneous catalysis throughout this book. Figure Catalysts are nanomaterials and catalysis is nanotechnology.
If we define nano-technology as the branch of materials science aiming to control material properties on the nanometer scale, then catalysis represents a field where nanomaterials have been applied commercially for about a century. Solid Acids and Bases: Their Catalytic Properties reviews developments in the studies of acidic and basic properties of solids, including the efficacy and special characteristics of solid acid and base catalysts.
This book discusses the determination of basic and acidic properties on solid surfaces and relationship between acid strength and acid amount. solid acid catalysis solid base catalysis Industrial processes in solid acids worldwide production by catalytic cracking: x tonnes/y 10 solid bases 14 solid acid-base bifunctional catalystsW.F.Hölderich, Applied Catalysis A () This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect: * Numerous catalytic reductions and oxidations methods * Solid-acid and solid-base catalysis * C-C bond formation reactions * Biocatalysis * Asymmetric catalysis * Novel reaction media like e.g.
ionic liquids, supercritical CO2 * Renewable raw materials Written by Roger A. The reactions catalyzed by solid base catalysts can be classified into three types: double bond isomerization, addition of anion and proton to various double bonds, and alcohol decomposition.
These are represented by 1-butene isomerization, hydrogenation of Cited by: Written by Roger A. Sheldon and his co-workers, this first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect: Numerous catalytic reductions and oxidations methods - Solid-acid and solid-base catalysis - C-C bond formation reactions.
Ebook > Sciences > Engineering / Technics > Chemical Engineering > Yoshio Ono & Hideshi Hattori: Solid Base Catalysis (PDF) Yoshio Ono & Hideshi Hattori Solid Base Catalysis. Support. Adobe DRM ( / – 3 customer ratings).
Roger Arthur Sheldon FRS FRSC is Emeritus Professor of Biocatalysis and Organic Chemistry at Delft University of Technology in the Netherlands.
Herman van Bekkum is the editor of Fine Chemicals through Heterogeneous Catalysis, published by Wiley. Metal Catalysis, Trends Across the Periodic Table, Some Frequently Used Concepts of Metal Catalysis, Catalysis by Ions at Surfaces.
Acid-Base Catalysis, Acid Catalysis in Solutions, Solid Acids, Carbenium Ion Reactions, Heterogeneous Catalysis and Solid Catalysts OLAF DEUTSCHMANN, Institut f€ur Technische Chemie und Polymerchemie, Universit €at Karlsruhe (TH), Enges- serstr. 20, Karlsruhe, Germany HELMUT KNOZINGER€, Department Chemie, Universit€at M €unchen, Butenandtstr.
5 – 13 (Haus E), M €unchen, Germany KARL KOCHLOEFL, Schwarzenbergstr. 15, Rosenheim, Germany The LibreTexts libraries are Powered by MindTouch ® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot.
We also acknowledge previous National Science Foundation support under grant numbers, and "This monograph follows up and complements another book by the same authors―Solid Base Catalysis― published in It represents a unique account of the historical background of heterogeneous catalysis and its industrial applications in petrochemistry and synthesis of Author: Hideshi Hattori, Yoshi Ono.
This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect:. Numerous catalytic reductions and oxidations methods. Solid-acid and solid-base catalysis. C-C bond formation reactions. Biocatalysis.
Asymmetric catalysis. Novel reaction media like e.g. ionic liquids, supercritical CO2. Renewable raw materials Written by Roger A. Solid base catalysis studied over the last a half of century is reviewed briefly including mainly those performed in our laboratories.
The review begins with advantages of solid base catalysts over.Abstract. In order to predict the capability of solid surface as base catalysts, the basic properties of the surfaces must be clarified.
The basic character or basicity includes the following factors: a) the number of basic sites, b) the origin or location of basic sites, and c) the base strength of basic sites. "This monograph follows up and complements another book by the same authors-Solid Base Catalysis- published in It represents a unique account of the historical background of heterogeneous catalysis and its industrial applications in petrochemistry and synthesis of .